Developing Technologies: Electrochemical PV cells

Unlike the crystalline and thin film solar cells that have solid-state light absorbing layers, electrochemical solar cells have their active component in a liquid phase. They use a dye sensitizer to absorb the light and create electron-hole pairs in a nanocrystalline titanium dioxide semiconductor layer. This is sandwiched in between a tin oxide coated glass sheet (the front contact of the cell) and a rear carbon contact layer, with a glass or foil backing sheet.

Some consider that these cells will offer lower manufacturing costs in the future because of their simplicity and use of cheap materials. The challenges of scaling up manufacturing and demonstrating reliable field operation of products lie ahead. However, prototypes of small devices powered by dye-sensitised nanocrystalline electrochemical PV cells are now appearing (120cm2 cells with an efficiency of 7%).

Developing Technologies: Concentrators

Solar cells usually operate more efficiently under concentrated light. This has led to the development of a range of approaches using mirrors or lenses to focus light on to specially designed cells and use heat sinks, or active cooling of the cells, to dissipate the large amount of heat that is generated. Unlike conventional flat plate PV arrays, concentrator systems require direct sunlight (clear skies) and will not operate under cloudy conditions. They generally follow the sun's path through the sky during the day using single-axis tracking. To adjust to the sun's varying height in the sky through the seasons, two-axis tracking is sometimes used.
Concentrators have not yet achieved widespread application in photovoltaics, but solar concentration has been widely used in solar thermal electricity generation technology where the generated heat is used to power a turbine.

Crystalline silicon solar cells

Historically, crystalline silicon (c-Si) has been used as the light-absorbing semiconductor in most solar cells, even though it is a relatively poor absorber of light and requires a considerable thickness (several hundred microns) of material. Nevertheless, it has proved convenient because it yields stable solar cells with good efficiencies (11-16%, half to two-thirds of the theoretical maximum) and uses process technology developed from the huge knowledge base of the microelectronics industry.

wo types of crystalline silicon are used in the industry. The first is monocrystalline, produced by slicing wafers (up to 150mm diameter and 350 microns thick) froma high-purity single crystal boule. The second is multicrystalline silicon, made by sawing a cast block of silicon first into bars and then wafers. The main trend in crystalline silicon cell manufacture is toward multicrystalline technology.

For both mono- and multicrystalline Si, a semiconductor homojunction is formed by diffusing phosphorus (an n-type dopant) into the top surface of the boron doped (p-type) Si wafer. Screen-printed contacts are applied to the front and rear of the cell, with the front contact pattern specially designed to allow maximum light exposure of the Si material with minimum electrical (resistive) losses in the cell.

The most efficient production cells use monocrystalline c-Si with laser grooved, buried grid contacts for maximum light absorption and current collection.

Some companies are productionizing technologies that by-pass some of the inefficiencies of the crystal growth/casting and wafer sawing route. One route is to grow a ribbon of silicon, either as a plain two-dimensional strip or as an octagonal column, by pulling it from a silicon melt.

Another is to melt silicon powder on a cheap conducting substrate. These processes may bring with them other issues of lower growth/pulling rates and poorer uniformity and surface roughness.

Each c-Si cell generates about 0.5V, so 36 cells are usually soldered together in series to produce a module with an output to charge a 12V battery. The cells are hermetically sealed under toughened, high transmission glass to produce highly reliable, weather resistant modules that may be warrantied for up to 25 years.

Thin film solar cells

The high cost of crystalline silicon wafers (they make up 40-50% of the cost of a finished module) has led the industry to look at cheaper materials to make solar cells.

The selected materials are all strong light absorbers and only need to be about 1micron thick, so materials costs are significantly reduced. The most common materials are amorphous silicon (a-Si, still silicon, but in a different form), or the polycrystalline materials: cadmium telluride (CdTe) and copper indium (gallium) diselenide (CIS or CIGS).

Each of these three is amenable to large area deposition (on to substrates of about 1 meter dimensions) and hence high volume manufacturing. The thin film semiconductor layers are deposited on to either coated glass or stainless steel sheet.

The semiconductor junctions are formed in different ways, either as a p-i-n device in amorphous silicon, or as a hetero-junction (e.g. with a thin cadmium sulphide layer) for CdTe and CIS. A transparent conducting oxide layer (such as tin oxide) forms the front electrical contact of the cell, and a metal layer forms the rear contact.

Thin film technologies are all complex. They have taken at least twenty years, supported in some cases by major corporations, to get from the stage of promising research (about 8% efficiency at 1cm2 scale) to the first manufacturing plants producing early product.

Amorphous silicon is the most well developed of the thin film technologies. In its simplest form, the cell structure has a single sequence of p-i-n layers. Such cells suffer from significant degradation in their power output (in the range 15-35%) when exposed to the sun.

The mechanism of degradation is called the Staebler-Wronski Effect, after its discoverers. Better stability requires the use of a thinner layers in order to increase the electric field strength across the material. However, this reduces light absorption and hence cell efficiency.

This has led the industry to develop tandem and even triple layer devices that contain p-i-n cells stacked one on top of the other. In the cell at the base of the structure, the a-Si is sometimes alloyed with germanium to reduce its band gap and further improve light absorption. All this added complexity has a downside though; the processes are more complex and process yields are likely to be lower.

In order to build up a practically useful voltage from thin film cells, their manufacture usually includes a laser scribing sequence that enables the front and back of adjacent cells to be directly interconnected in series, with no need for further solder connection between cells.

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Definition of a Solar Cell - History of Solar Cells

A solar cell is any device that directly converts the energy in light into electrical energy through the process of photovoltaics. The development of solar cell technology begins with the 1839 research of French physicist Antoine-César Becquerel. Becquerel observed the photovoltaic effect while experimenting with a solid electrode in an electrolyte solution when he saw a voltage develope when light fell upon the electrode.

According to Encyclopedia Britannica the first genuine solar cell was built around 1883 by Charles Fritts, who used junctions formed by coating selenium (a semiconductor) with an extremely thin layer of gold.

Russell Ohl - Silicon Solar Cell

Early solar cells, however, had energy conversion efficiencies of under one percent. In 1941, the silicon solar cell was invented by Russell Ohl.
Gerald Pearson, Calvin Fuller and Daryl Chapin - Efficient Solar Cells

In 1954, three American researchers, Gerald Pearson, Calvin Fuller and Daryl Chapin, designed a silicon solar cell capable of a six percent energy conversion efficiency with direct sunlight.
The three inventors created an array of several strips of silicon (each about the size of a razorblade), placed them in sunlight, captured the free electrons and turned them into electrical current. They created the first solar panels. Bell Laboratories in New York announced the prototype manufacture of a new solar battery. Bell had funded the research. The first public service trial of the Bell Solar Battery began with a telephone carrier system (Americus, Georgia) on October 4 1955.

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